Hydrogen embrittlement he also known as hydrogen assisted cracking hac and hydrogeninduced cracking hic, describes the embrittling of metal after. As we know that both form of cracking are due to the absorption of atomic hydrogen that is produced by. May 22, 2018 hic, hydrogen induced cracking, hydrogen induced cracking test, ultrasonic, cscan, cscan. Hydrogen combines with carbon within the alloy and forms methane. By using dent specimen, hydrogeninduced cracking hic cracks were found to initiate at martensiteaustenite interfaces and then. Hydrogeninduced craking hic, also referred to as hydrogen stress cracking or static fatigue, is a typical form of hydrogen embrittlement. Hydrogen cracking may also be called cold cracking or delayed cracking. During investigation many cracks were observed on the inner surface of the valve body grown from the surface pits.
Unstressed test specimens are exposed to a solution at temperature of. Hydrogen trapping sites and hydrogeninduced cracking in. A small number of duplex and superduplex stainless steel components have failed in subsea service due to hydrogen induced stress cracking hisc. Sohic is a type of cracking that can easily lead to failure and needs to be mitigated. Hydrogeninduced cracking hic definition hydrogeninduced cracking hic refers to the internal cracks brought about by. Two types of cracking, namely sulphide stress cracking ssc and hydrogen induced cracking hic, were evaluated in linepipe steels using nace standard solution to establish the metallurgical parameters that control hic and ssc. Hydrogen effect is greater near room temperature and decreases with increasing strain rate. Investigating the effect of residual stress on hydrogen cracking in multipass robotic welding through process compatible nondestructive testing. Stresscorrosion cracking scc and hydrogen embrittlement are differentiated by their responses to the applied current and mode of cracking. Masterhic is masteel uk limiteds designation for hic steel for fine grain pressure vessel steels offering specific and superior properties for sour gas application.
Hic usually occurs due to the effects of aqueous hydrogen charging of steel in wet h2s refinery process environments. Woollin p and murphy w, hydrogen embrittlement stress cracking of superduplex stainless steel, proc conf corrosion 2001, nace international, paper 01018. Hydrogen induced cracking hic on steel for corrosion. Hydrogeninduced cracking is a phenomenon that causes metal alloys to fracture, most. If you recall, we mentioned you need all three factors to be present in order to have hic. How to super clean the inside of your windshield no streaks duration. Our last post factors influencing hydrogen induced cracking went over the factors that contribute to hydrogeninduced cracking. Methods for detection of hidden corrosion, measurement of material degrada. Here, the anodic dissolution process contributes to the progress of cracks. Stress corrosion cracking scc is the growth of crack formation in a corrosive environment. Hisc hydrogen induced stress cracking design and material considerations 1 day course if you would like further information on this course, please contact yeechin tang. Hydrogen induced cracking hic or stepwise cracking swc is a specific kind of hydrogen provoked damage in carbon and low alloy steels operating in hydrogen sulphide containing environments, especially in steels used for pipelines and pressure vessels in oil and refinery industry. Also high strength structural steels which are welded are exposed to a certain hydrogen pickup which means a risk at fracture and blistering due to hic.
According to iso 15156, hydrogen induced cracking hic is defined as planar cracking that occurs in carbon and low alloy steels when atomic hydrogen diffuses into the steel and then combines to form molecular hydrogen at trap sites inclusions or voids. Metallurgical factors in stress corrosion cracking scc and hydrogeninduced cracking hic article in journal of solid state electrochemistry 7. The significance of these failures has led to research to define critical loading conditions for hisc, to allow confident design of components in future. Effect of nonmetallic inclusions on hydrogen induced cracking. Hisc abbreviation stands for hydrogen induced stress cracking. Hic test, hydrogen induced cracking test, step wise.
It can occur at relatively low temperatures, largely as a result of atomic hydrogen from wet h2s corrosion reactions which enter the steel and collect at inclusions or. Mar 25, 2009 nonmetallic inclusions can affect resistance of steels to both general and localized corrosion, including pitting corrosion, stress corrosion cracking scc, and hydrogeninduced cracking hic. The most common grades of hydrogen induced crack resistant steel plates is a516 to asmeastm standards. Cracking occurs due to a significant loss in ductility. Defects hydrogen cracks in steels identification twi. More often, fracture occurs at sustained loads below the yield strength of the material. Sulfide stress cracking ssc vs hydrogen induced cracking hlc posted in refining, hydrocarbons, oil, and gas. Nace international has adopted the term hydrogen induced cracking hic.
Hydrogen induced craking hic, also referred to as hydrogen stress cracking or static fatigue, is a typical form of hydrogen embrittlement. Hic, hydrogen induced cracking, hydrogen induced cracking test, ultrasonic, cscan, cscan. It was not until much later, however, that hic started to be investigated and gained recognition as a potential problem in pipelines as a result of pipeline failures. By using dent specimen, hydrogen induced cracking hic cracks were found to initiate at martensiteaustenite interfaces and then propagate through retained austenite and martensite. Hydrogen induced cracking of low strength steels in. The principal distinguishing feature of this type of crack is that it occurs in ferritic steels, most often immediately on welding or a short time after welding. It is made up of a series of hic hydrogen induced cracking cracks that are stacked perpendicularly in the direction of through wall cracks and driven by high residual or applied stresses. Hydrogen induced cold cracking in a low alloy steel. This is a type of deterioration which can be linked to corrosion and corrosioncontrol processes. According to iso 15156, hydrogeninduced cracking hic is defined as planar cracking that occurs in carbon and low alloy steels when atomic hydrogen diffuses into the steel and then combines to form molecular hydrogen at trap sites inclusions or voids. Sohlc appears to be related to segregation of microalloying elements in the banded steel microstructure.
Metallurgical factors in stress corrosion cracking scc and. Specificationsgrades asmeastm saa 516 grades 606570. Elements hic tests evaluate material susceptibility to hydrogen induced cracking in a sour environment in accordance with nace tm0284. Unstressed test specimens are exposed to a solution at temperature of 25deg cent with continuous h2s gas flow. Hydrogen induced cracking of subsea duplex stainless steel twi. Hydrogeninduced microcracking produces a chemical reaction. Nonmetallic inclusions can affect resistance of steels to both general and localized corrosion, including pitting corrosion, stress corrosion cracking scc, and hydrogeninduced cracking hic. Hydrogen induced crack resistant steel plates is used by boiler makers and fabricators when hydrogen induced cracking is a big risk. The test procedure involves the evaluation of resistance of pressure vessel steel plate and pipework steels to hydrogen reduced cracking caused by hydrogen absorption from aqueous sulfide corrosion. There are several categories of hydrogen phenomena that are localized in nature. Recent experience has demonstrated the risk of sscc and hic, sometimes known as hydrogen embrittlement he, of low strength steels subject to high residual stress derived from fabrication techniques. The results indicate that flow control valve body failed due to combination of hydrogen induced corrosion cracking hicc and sulfide stress corrosion cracking sscc.
The ssc of medium strength steels has been a continuing source of trouble in the oil fields, and from these troubles has evolved in international standards 6. Hydrogen trapping sites and hydrogeninduced cracking in high. Sulfide stress corrosion cracking and hydrogen induced. The methane molecules create a pressure which leads. The hydrogen atom is the smallest of all atoms and hydrogen attack is similarly insidious and hidden from simple inspection techniques. Hydrogen induced cracking steel features, applications. The path of crack growth in hydrogen embrittled steels is a function of the stress intensity factor, k mpavm. Hydrogen induced cracking hic is a common form of wet h2s cracking caused by the blistering of a metal due to a high concentration of hydrogen.
The methane molecules create a pressure which leads to embrittlement and even cracking of the metal. Hydrogen induced cracking hic damage is a degradation mechanism active in the oil and gas industry. Hic testing is recommended to evaluate the resistance of pipeline and pressure vessel plate steels to hydrogen induced cracking corrosion caused by hydrogen absorption from aqueous sulfide corrosion. In the presence of h 2 s, hydrogen atoms originating from the cathodic reduction reaction driving the anodic dissolution reaction can diffuse into the steel, resulting in cracking mechanisms such as hydrogeninduced cracking hic, sulphide stress cracking ssc and stressoriented hydrogeninduced cracking sohic. What is the abbreviation for hydrogen induced stress cracking. Hydrogen embrittlement he also known as hydrogen assisted cracking hac and hydrogeninduced cracking hic, describes the embrittling of metal after being exposed to hydrogen. Hydrogeninduced cracking hic in steel is a risk problem when steels are charged with hydrogen in service as in various hydrogen sulfide environments like sour oil and gas wells and some power plants. Hydrogen induced stress cracking hisc resistance and. Naceastm g193 1 includes the following description of hydrogen blistering. Scc is highly chemically specific in that certain alloys are likely to undergo scc only when exposed to a small number of chemical environments. Sulfide stress cracking ssc vs hydrogen induced cracking. Because stress corrosion cracks frequently initiate at pits, and pits nucleate at sulfides, the presence of sulfides is likely to affect the scc process. It is often assumed that hic is just a subcategory of sulfide stress cracking.
Cosasco provides hydrogen monitoring solutions for corrosion control such as hydrogen blistering hydrogen induced cracking hic on steel. Corrosionpedia feed of the terms and educational resources for corrosion professionals. It is characterized by the brittle fracture of a normally ductile alloy under sustained load in the presence of hydrogen. Hydrogen induced cracking steel features, applications and. In the presence of h 2 s, hydrogen atoms originating from the cathodic reduction reaction driving the anodic dissolution reaction can diffuse into the steel, resulting in cracking mechanisms such as hydrogen induced cracking hic, sulphide stress cracking ssc and stress oriented hydrogen induced cracking sohic. Hydrogen induced cracking hic from advanced ndt solutions.
Macleod, david lines, momchil vasilev, zhen qiu, carmelo mineo, stephen g. If applied current makes the specimen more anodic and accelerates cracking, it is a case of stresscorrosion cracking. The scc has been studied extensively in the literature. Presentation on hydrogen induced cracking and sulfide stress cracking by denzil d souza contents what is hicssc. Hydrogeninduced cracking susceptibility in highstrength. Nace international has adopted the term hydrogeninduced cracking hic. Pdf hydrogen induced cracking safe materials operating limits. The hydrogeninduced cracking hic susceptibility of weld met als of hightensile strength ranging from 70 to 100 kgfmm2 100 to 143 ksi was investigated to estimate the lowest possi ble preheat and interpass temperatures to prevent cracking. It can lead to unexpected sudden failure of normally ductile metal alloys subjected to a tensile stress, especially at elevated temperature. Metallurgical factors in stress corrosion cracking scc.
It involves the ingress of hydrogen into a component, an event that can seriously reduce the ductility and loadbearing capacity, cause cracking and catastrophic brittle failures at stresses below the yield stress of susceptible materials. Hydrogen induced cracking hic is a failure mechanism resulting in sudden exposures and cracks due to growing laminations inside the base material and welds. Hydrogen induced cracking of subsea duplex stainless steel. Hic steel is plate which is tested to reduce the effects of hydrogen induced cracking in a wet h 2 s or sour service environment. O ur last post factors influencing hydrogen induced cracking went over the factors that contribute to hydrogeninduced cracking. Hydrogeninduced cracking hic refers to the internal cracks brought about by material trapped in budding hydrogen atoms. Investigating the effect of residual stress on hydrogen. Preventing hydrogen induced cracking welding answers.
Two types of cracking, namely sulphide stress cracking ssc and hydrogeninduced cracking hic, were evaluated in linepipe steels using nace standard solution to establish the metallurgical parameters that control hic and ssc. Stress orientated hydrogen induced cracking occurs in the area of grain enlargement in weld heat affected zones. Quantitative experiments indicate a threshold hydrogen concentration for hic below which no cracking will initiate. Nov 26, 2017 hydrogen embrittlement,superplasticity gate. In essence, hic testing is actually an evaluation of the steel for susceptibility to hydrogen embrittlement.
Stressoriented hydrogen induced cracking sohic is a common, insidious form of wet h2s cracking. Woollin p and gregori a, avoiding hydrogen embrittlement stress cracking of ferritic austenitic stainless steels under cathodic protection, proc conf omae 2004, paper 51203. Factors influencing hydrogen induced cracking welding. Hydrogen induced crack resistant hic steel plate brown mcfarlane offers the widest range of carbon and stainless steel plate, available exstock. It is a complex form of corrosion that can be extremely costly and. Examples of hydrogen embrittlement are cracking of weldments or hardened steels when exposed to conditions which inject hydrogen into the component. Hydrogen induced cracking hic and stressoriented hydrogen induced cracking sohic. Jun 03, 2018 hydrogeninduced cracking hic refers to the internal cracks brought about by material trapped in budding hydrogen atoms. The formation of subsurface planar cavities, called hydrogen blisters, in a metal resulting from excessive internal hydrogen pressure. Hydrogeninduced cracking hic is the stepwise internal cracks that connect adjacent hydrogen blisters on different planes in the metal, or to the metal surface. The list of acronyms and abbreviations related to hisc hydrogen induced stress cracking. Processes or conditions involving wet hydrogen sulfide, i. The combination of applied and high residual stress results in work hardening of the stronger bands resulting in ssc.
Corrosionpedia what is hydrogeninduced cracking hic. Nondestructive evaluation methods for characterization of corrosion. Cracks can develop by both transgranular and intergranular paths. It is a complex process that is not completely understood because of the variety and complexity of mechanisms that can lead to embrittlement. Hydrogen embrittlement occurs in a number of forms but the common features are an applied tensile stress and hydrogen dissolved in the metal. It involves atomic hydrogen, which is the smallest atom, that diffuses into a metallic structure.
Hydrogen induced cracking is a mechanical fracture caused by penetration and diffusion of atomic hydrogen into the internal structure of steel, which changes into molecular. Hydrogen blistering has been recognized since the 1940s as a problem in vessel handling sour products. Hisc hydrogen induced stress considerations 1 day course. Hisc hydrogen induced stress cracking all acronyms. Factors influencing hydrogen induced cracking welding answers. Dec 21, 2016 hydrogen induced cracking hic and stressoriented hydrogen induced cracking sohic. Hydrogeninduced cracking an overview sciencedirect topics. The blistering damage tends to form parallel to the surface and to the direction of hoop stress. Hic is often fairly innocuous but not always, while sohic is a type of cracking that can easily lead to. It is also called hydrogen assisted cracking hac and delayed cracking since it does not occur right after welding, but a few hours or days after the weld has completely cooled down to ambient temperature. Hydrogeninduced cracking hic is a far too common type of failure. Pdf hydrogen induced cracking safe materials operating.